Thermodynamics: Diagram-Based Questions (3)

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Question

One mole of an ideal monoatomic gas undergoes a cyclic process ABCAA \to B \to C \to A on a PP-VV diagram, where:

  • A=(P0,V0)A = (P_0, V_0)
  • B=(2P0,V0)B = (2P_0, V_0) (isochoric heating)
  • C=(P0,2V0)C = (P_0, 2V_0) (then a straight line back to AA)

Find the net work done in the cycle and the efficiency. Take P0V0=RT0P_0 V_0 = R T_0.

Solution — Step by Step

A → B (isochoric, VV constant): WAB=0W_{AB} = 0.

B → C (straight line on PP-VV): work = area under the curve = trapezoidal area between V=V0V = V_0 and V=2V0V = 2V_0.

WBC=12(2P0+P0)(2V0V0)=32P0V0W_{BC} = \tfrac{1}{2}(2P_0 + P_0)(2V_0 - V_0) = \tfrac{3}{2}P_0 V_0

C → A (isobaric at P0P_0, VV goes from 2V02V_0 to V0V_0):

WCA=P0(V02V0)=P0V0W_{CA} = P_0(V_0 - 2V_0) = -P_0 V_0

Wnet=0+32P0V0P0V0=12P0V0W_{net} = 0 + \tfrac{3}{2}P_0 V_0 - P_0 V_0 = \tfrac{1}{2}P_0 V_0

This matches the enclosed triangular area on the PP-VV diagram (vertices at AA, BB, CC): 12V0P0=12P0V0\tfrac{1}{2}\cdot V_0 \cdot P_0 = \tfrac{1}{2}P_0V_0. ✓

Compute temperatures: TA=P0V0/R=T0T_A = P_0V_0/R = T_0, TB=2P0V0/R=2T0T_B = 2P_0V_0/R = 2T_0, TC=2P0V0/R=2T0T_C = 2P_0V_0/R = 2T_0.

So heating happens during A → B (and partially in B → C, where TT rises and falls). Heat absorbed only counts where dQ>0dQ > 0.

For monoatomic gas: CV=32RC_V = \tfrac{3}{2}R, CP=52RC_P = \tfrac{5}{2}R.

QAB=nCVΔT=132RT0=32P0V0Q_{AB} = nC_V \Delta T = 1 \cdot \tfrac{3}{2}R \cdot T_0 = \tfrac{3}{2}P_0V_0

For B → C, careful: ΔU=nCV(TCTB)=0\Delta U = nC_V(T_C - T_B) = 0 (since TC=TBT_C = T_B). QBC=ΔU+WBC=0+32P0V0=32P0V0Q_{BC} = \Delta U + W_{BC} = 0 + \tfrac{3}{2}P_0V_0 = \tfrac{3}{2}P_0V_0. Heat absorbed.

So total heat absorbed Qin=32P0V0+32P0V0=3P0V0Q_{in} = \tfrac{3}{2}P_0V_0 + \tfrac{3}{2}P_0V_0 = 3P_0V_0.

η=WnetQin=P0V0/23P0V0=1616.7%\eta = \frac{W_{net}}{Q_{in}} = \frac{P_0V_0/2}{3P_0V_0} = \frac{1}{6} \approx 16.7\%

Final answer: Wnet=12P0V0W_{net} = \tfrac{1}{2}P_0V_0, η=16\eta = \tfrac{1}{6}.

Why This Works

Net work in a cyclic process = enclosed area on the PP-VV diagram, regardless of the path. Clockwise loops give positive work (heat engine); anticlockwise loops give negative work (refrigerator).

Efficiency uses only the heat absorbed (where dQ>0dQ > 0). Heat rejected during the cooling legs is wasted — it doesn’t go into the denominator.

JEE Main 2024 Shift 1 had nearly this exact problem with rectangular cycle. Students who memorised “efficiency = W/QinW/Q_{in}” without identifying which legs absorb heat got it wrong.

Alternative Method

For each leg, compute QQ from Q=ΔU+WQ = \Delta U + W, then sum positive contributions for QinQ_{in}. Same result.

Students often write η=Wnet/(QinQout)\eta = W_{net}/(Q_{in} - Q_{out}). That’s wrong — Wnet=QinQoutW_{net} = Q_{in} - Q_{out} already (first law over the cycle, since ΔU=0\Delta U = 0). The denominator must be QinQ_{in} alone.

Common Mistake

For diagram-based thermodynamics questions, students frequently add all heat values (including those where heat is released) into QinQ_{in}. Only count legs where dQ>0dQ > 0. The fix: tabulate QQ for each leg with sign, then sum only positives.

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