Question
One mole of an ideal monoatomic gas undergoes a cyclic process A→B→C→A on a P-V diagram, where:
- A=(P0,V0)
- B=(2P0,V0) (isochoric heating)
- C=(P0,2V0) (then a straight line back to A)
Find the net work done in the cycle and the efficiency. Take P0V0=RT0.
Solution — Step by Step
A → B (isochoric, V constant): WAB=0.
B → C (straight line on P-V): work = area under the curve = trapezoidal area between V=V0 and V=2V0.
WBC=21(2P0+P0)(2V0−V0)=23P0V0
C → A (isobaric at P0, V goes from 2V0 to V0):
WCA=P0(V0−2V0)=−P0V0
Wnet=0+23P0V0−P0V0=21P0V0
This matches the enclosed triangular area on the P-V diagram (vertices at A, B, C): 21⋅V0⋅P0=21P0V0. ✓
Compute temperatures: TA=P0V0/R=T0, TB=2P0V0/R=2T0, TC=2P0V0/R=2T0.
So heating happens during A → B (and partially in B → C, where T rises and falls). Heat absorbed only counts where dQ>0.
For monoatomic gas: CV=23R, CP=25R.
QAB=nCVΔT=1⋅23R⋅T0=23P0V0
For B → C, careful: ΔU=nCV(TC−TB)=0 (since TC=TB). QBC=ΔU+WBC=0+23P0V0=23P0V0. Heat absorbed.
So total heat absorbed Qin=23P0V0+23P0V0=3P0V0.
η=QinWnet=3P0V0P0V0/2=61≈16.7%
Final answer: Wnet=21P0V0, η=61.
Why This Works
Net work in a cyclic process = enclosed area on the P-V diagram, regardless of the path. Clockwise loops give positive work (heat engine); anticlockwise loops give negative work (refrigerator).
Efficiency uses only the heat absorbed (where dQ>0). Heat rejected during the cooling legs is wasted — it doesn’t go into the denominator.
JEE Main 2024 Shift 1 had nearly this exact problem with rectangular cycle. Students who memorised “efficiency = W/Qin” without identifying which legs absorb heat got it wrong.
Alternative Method
For each leg, compute Q from Q=ΔU+W, then sum positive contributions for Qin. Same result.
Students often write η=Wnet/(Qin−Qout). That’s wrong — Wnet=Qin−Qout already (first law over the cycle, since ΔU=0). The denominator must be Qin alone.
Common Mistake
For diagram-based thermodynamics questions, students frequently add all heat values (including those where heat is released) into Qin. Only count legs where dQ>0. The fix: tabulate Q for each leg with sign, then sum only positives.