Photoelectric Effect: Tricky Questions Solved (4)

easy 2 min read

Question

The work function of a metal is ϕ=2.5 eV\phi = 2.5\text{ eV}. Light of wavelength λ=400 nm\lambda = 400\text{ nm} falls on the surface. (a) Find the maximum kinetic energy of the emitted photoelectrons. (b) Find the stopping potential. (c) What is the threshold wavelength for this metal? Use hc=1240 eV⋅nmhc = 1240\text{ eV·nm}.

Solution — Step by Step

Ephoton=hcλ=1240400=3.1 eVE_{\text{photon}} = \frac{hc}{\lambda} = \frac{1240}{400} = 3.1\text{ eV}

By Einstein’s photoelectric equation:

KEmax=Ephotonϕ=3.12.5=0.6 eVKE_{\max} = E_{\text{photon}} - \phi = 3.1 - 2.5 = 0.6\text{ eV}

The stopping potential VsV_s in volts equals the maximum KE in eV (numerically), since eVs=KEmaxeV_s = KE_{\max}.

So Vs=0.6 VV_s = 0.6\text{ V}.

At threshold, photon energy equals work function: hc/λ0=ϕhc/\lambda_0 = \phi.

λ0=hcϕ=12402.5=496 nm\lambda_0 = \frac{hc}{\phi} = \frac{1240}{2.5} = 496\text{ nm}

KEmax=0.6 eVKE_{\max} = 0.6\text{ eV}, Vs=0.6 VV_s = 0.6\text{ V}, λ0=496 nm\lambda_0 = 496\text{ nm}.

Why This Works

Einstein’s view: light energy comes in quanta of hfhf. Each photon either ejects one electron (if it has enough energy) or does nothing — intensity controls how many photons arrive per second, not their individual energies.

The work function is the minimum energy needed to liberate an electron from the metal. Anything beyond ϕ\phi becomes kinetic energy of the ejected electron.

Alternative Method

Using SI: Ephoton=hfE_{\text{photon}} = hf with h=6.63×1034 J⋅sh = 6.63 \times 10^{-34}\text{ J·s} and f=c/λf = c/\lambda. Convert eV to joules at the end. The hc=1240 eV⋅nmhc = 1240\text{ eV·nm} shortcut saves a unit-conversion step and is universally accepted in JEE/NEET.

Common Mistake

Adding intensity to the equation. Doubling the intensity doubles the photoelectric current but does NOT change KEmaxKE_{\max} or stopping potential. Many students think “more light = faster electrons” — this was the classical-physics prediction that the photoelectric effect actually disproved.

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