Photoelectric Effect: PYQ Walkthrough (3)

hard 3 min read

Question

(JEE Main 2024 Shift 1 pattern) Light of wavelength 400400 nm falls on a metal of work function 2.02.0 eV. Find (a) the maximum kinetic energy of the emitted photoelectrons, (b) the stopping potential, (c) the threshold wavelength for this metal. Use hc=1240hc = 1240 eV·nm.

Solution — Step by Step

Ephoton=hcλ=1240400=3.1 eVE_{\text{photon}} = \frac{hc}{\lambda} = \frac{1240}{400} = 3.1 \text{ eV}

Using hc=1240hc = 1240 eV·nm with λ\lambda in nm gives the answer directly in eV — much faster than SI units for this chapter.

KEmax=Ephotonϕ=3.12.0=1.1 eVKE_{\max} = E_{\text{photon}} - \phi = 3.1 - 2.0 = 1.1 \text{ eV}

Stopping potential V0V_0 is the voltage that stops even the fastest electron: eV0=KEmaxeV_0 = KE_{\max}. Since KEmax=1.1KE_{\max} = 1.1 eV, we directly get:

V0=1.1 VV_0 = 1.1 \text{ V}

The trick: in eV units, the numerical value of KEKE in eV equals V0V_0 in volts.

At threshold, photon energy equals work function exactly: hc/λ0=ϕhc/\lambda_0 = \phi.

λ0=hcϕ=12402.0=620 nm\lambda_0 = \frac{hc}{\phi} = \frac{1240}{2.0} = 620 \text{ nm}

Final Answer: (a) KEmax=1.1KE_{\max} = 1.1 eV. (b) V0=1.1V_0 = 1.1 V. (c) λ0=620\lambda_0 = 620 nm.

Why This Works

Einstein’s equation says one photon ejects one electron, with the photon’s energy split between overcoming the work function and giving the electron kinetic energy. There is no time-delay or accumulation — either the photon has enough energy (ϕ\geq \phi) or it doesn’t.

The threshold wavelength is the longest wavelength that can still eject electrons. Anything longer than 620620 nm here (e.g., red light at 700700 nm) produces no photoelectrons regardless of intensity — a fact that classical wave theory could not explain and which earned Einstein the Nobel Prize.

Alternative Method

Using SI units: E=(6.63×1034)(3×108)/(400×109)=4.97×1019E = (6.63 \times 10^{-34})(3 \times 10^8)/(400 \times 10^{-9}) = 4.97 \times 10^{-19} J. Convert to eV by dividing by 1.6×10191.6 \times 10^{-19}: 3.1\approx 3.1 eV. Same answer, three times more arithmetic. Stick with hc=1240hc = 1240 eV·nm in this chapter.

Plugging wavelength in metres but hchc in eV·nm (or vice versa) is the most common slip. Either use SI throughout, or stay entirely in eV-nm. Mixing units gives a 10910^9 error.

Stopping potential depends only on the photon’s frequency (and the metal’s work function), not on light intensity. Intensity changes only the number of photoelectrons, not their maximum energy. This is the conceptual question NEET asks every year.

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