Nuclei: Edge Cases and Subtle Traps (2)

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Question

A radioactive sample contains N0N_0 nuclei of species A with half-life TT. Species A decays into species B, which is also radioactive with half-life 2T2T. Initially, only A is present. Find the time at which the number of B nuclei is maximum, and the number of A nuclei at that instant.

Solution — Step by Step

Let λA=ln2/T\lambda_A = \ln 2 / T and λB=ln2/(2T)=λA/2\lambda_B = \ln 2 / (2T) = \lambda_A / 2.

dNAdt=λANA,dNBdt=λANAλBNB\frac{dN_A}{dt} = -\lambda_A N_A, \quad \frac{dN_B}{dt} = \lambda_A N_A - \lambda_B N_B
NA(t)=N0eλAtN_A(t) = N_0 e^{-\lambda_A t}

NBN_B is maximum when dNB/dt=0dN_B/dt = 0, which means production rate = decay rate:

λANA=λBNB\lambda_A N_A = \lambda_B N_B

Solving the linear ODE with NB(0)=0N_B(0) = 0:

NB(t)=λAN0λAλB(eλBteλAt)N_B(t) = \frac{\lambda_A N_0}{\lambda_A - \lambda_B}\left(e^{-\lambda_B t} - e^{-\lambda_A t}\right)

Differentiate and set to zero, or use the condition above. From step 3:

λAeλAt=λBλAλAλB(eλBteλAt)\lambda_A e^{-\lambda_A t} = \lambda_B \cdot \frac{\lambda_A}{\lambda_A - \lambda_B}\left(e^{-\lambda_B t} - e^{-\lambda_A t}\right)

Simplify:

eλAt(λAλB)=λB(eλBteλAt)e^{-\lambda_A t}(\lambda_A - \lambda_B) = \lambda_B(e^{-\lambda_B t} - e^{-\lambda_A t}) λAeλAt=λBeλBt\lambda_A e^{-\lambda_A t} = \lambda_B e^{-\lambda_B t} t=ln(λA/λB)λAλBt = \frac{\ln(\lambda_A/\lambda_B)}{\lambda_A - \lambda_B}

λA/λB=2\lambda_A/\lambda_B = 2. λAλB=λA/2=ln2/(2T)\lambda_A - \lambda_B = \lambda_A/2 = \ln 2/(2T).

tmax=ln2ln2/(2T)=2Tt_{max} = \frac{\ln 2}{\ln 2/(2T)} = 2T

At t=2Tt = 2T: NA=N0eλA(2T)=N0e2ln2=N0/4N_A = N_0 e^{-\lambda_A (2T)} = N_0 e^{-2\ln 2} = N_0 / 4.

Final answer: tmax=2Tt_{max} = 2T, NA(tmax)=N0/4N_A(t_{max}) = N_0/4.

Why This Works

When B is at its peak, the rate of B production from A exactly cancels B’s own decay. This is a quasi-steady-state instant, not an equilibrium — both populations keep changing.

The general formula tmax=ln(λA/λB)/(λAλB)t_{max} = \ln(\lambda_A/\lambda_B)/(\lambda_A - \lambda_B) is worth memorising for JEE Advanced.

Alternative Method

Numerical: tabulate NAN_A and NBN_B in steps of T/4T/4 and locate the peak. Slow but bulletproof.

Students assume B reaches maximum when all of A has decayed. Wrong — A decays asymptotically, so “all A gone” never happens in finite time. B peaks much earlier, when its own decay catches up with its production.

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