Question
A radioactive sample contains N0 nuclei of species A with half-life T. Species A decays into species B, which is also radioactive with half-life 2T. Initially, only A is present. Find the time at which the number of B nuclei is maximum, and the number of A nuclei at that instant.
Solution — Step by Step
Let λA=ln2/T and λB=ln2/(2T)=λA/2.
dtdNA=−λANA,dtdNB=λANA−λBNB
NA(t)=N0e−λAt
NB is maximum when dNB/dt=0, which means production rate = decay rate:
λANA=λBNB
Solving the linear ODE with NB(0)=0:
NB(t)=λA−λBλAN0(e−λBt−e−λAt)
Differentiate and set to zero, or use the condition above. From step 3:
λAe−λAt=λB⋅λA−λBλA(e−λBt−e−λAt)
Simplify:
e−λAt(λA−λB)=λB(e−λBt−e−λAt)
λAe−λAt=λBe−λBt
t=λA−λBln(λA/λB)
λA/λB=2. λA−λB=λA/2=ln2/(2T).
tmax=ln2/(2T)ln2=2T
At t=2T: NA=N0e−λA(2T)=N0e−2ln2=N0/4.
Final answer: tmax=2T, NA(tmax)=N0/4.
Why This Works
When B is at its peak, the rate of B production from A exactly cancels B’s own decay. This is a quasi-steady-state instant, not an equilibrium — both populations keep changing.
The general formula tmax=ln(λA/λB)/(λA−λB) is worth memorising for JEE Advanced.
Alternative Method
Numerical: tabulate NA and NB in steps of T/4 and locate the peak. Slow but bulletproof.
Students assume B reaches maximum when all of A has decayed. Wrong — A decays asymptotically, so “all A gone” never happens in finite time. B peaks much earlier, when its own decay catches up with its production.