CBSENEETJEEClass 11

What is enthalpy?

Answer

Enthalpy (H) is the total heat content of a system at constant pressure, defined as H = U + PV, where U is internal energy.

The working

Definition

Enthalpy is a thermodynamic state function representing the heat content of a system measured at constant pressure.

Formula

It is given by H = U + PV, where U is internal energy, P is pressure, and V is volume.

Change in enthalpy

At constant pressure, the heat absorbed or released equals the enthalpy change, ΔH = qp.

Sign convention

ΔH is negative for exothermic reactions (heat released) and positive for endothermic reactions (heat absorbed).

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